7–10 Apr 2025
Main Physics Building
Europe/London timezone

Implementation of Numerical Functional Derivatives for GGA Functionals in the Yambo Code.

8 Apr 2025, 14:18
3m
Bell Lecture Theatre (Main Physics Building)

Bell Lecture Theatre

Main Physics Building

School of Mathematics and Physics Queen's University Belfast University Rd, Belfast BT7 1NN, United Kingdom
Poster Flash Talks

Speaker

Mr Petru Milev (Istituto di Struttura della Materia-CNR (ISM-CNR))

Description

Density Functional Theory (DFT) is a widely-used computational approach for investigating electronic properties of materials, relying heavily on the choice of appropriate exchange-correlation functionals. Among these functionals, the generalized gradient approximation (GGA) is widely used due to its effectiveness in capturing electron exchange-correlation effects beyond local approximations. However, calculating numerical functional derivatives directly from their definition is impractical, as it involves introducing separate delta-like perturbations and evaluating derivatives individually at every point in real space. In this poster, we present an efficient alternative approach to compute the functional derivatives of the spin-polarized exchange-correlation potential ($V_{xc}$) by taking advantage of already existing subroutines in the Yambo software. We demonstrate that accurate numerical functional derivatives can be obtained through numerical partial derivatives of $V_{xc}$. By appropriately combining those, we achieve high-accuracy functional derivatives of exchange-correlation potential suitable for spectral analyses and study of magnon interactions using GGA functionals.

Authors

Mr Petru Milev (Istituto di Struttura della Materia-CNR (ISM-CNR)) Myrta Gruening (Queen’s University Belfast) Dr Davide Sangalli (Istituto di Struttura della Materia (ISM) - CNR)

Presentation materials

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